Yes, as is sometimes the case with syndicated TV series of the 1950s. Various DVD releases of varying quality have been release by various DVD companies. It can also be viewed on the Internet Archive and on YouTube.
The adventures of master detective Sherlock Holmes as he and his assistant, Dr. Watson--and, somewhat reluctantly, the bumbling Inspector Lestrade--battle criminals in London.
Who are the characters in Sherlock Holmes?
Dr. John Watson, Inspector Lestrade, Brighton, Charlie Willis, Comte de Passevant, Count Tennow, Dr. Dimanche, Duncan Ross, Harry Crocker, Insp. MacDougal, and others